Draw the kinetic and thermodynamic addition products formed when one equivalent of HBr reacts with the diene .

See explanation and images attached

Explanation:

The addition of HBr to the diene could yield either a kinetic or thermodynamic product. The kinetic product is formed faster while the thermodynamic product is more stable and formed at equilibrium.

Recall that the alkene that is surrounded by more alkyl groups is more stable. Also, the carbocation undergoes rearrangement to form a more stable carbocation intermediate that ultimately leads to the formation of the thermodynamic (1,4) product which predominates.

The structures of the two products are shown in the image attached to this answer.

the volume increases

as given the equation is

2al + 6 hcl > 2 alcl3 + 3 h2(g)

as per equation two moles of aluminum reacts with six moles of hcl to give two moles of alcl3 and three moles of hydrogen gas

given: three moles of al are present and 7 moles of hcl

for three moles of aluminum nine moles of hcl will be required

however as 7 moles of hcl are present so the limiting reagent is hcl

hcl is going to decide the number of moles of product formed

when six moles of hcl are present = 3 moles of h2 are formed

when one mole of hcl is present == 3/6 mole sof h2 will be formed

when 7 moles of hcl are present = 3 x 7/ 6 moles of h2 will be formed = 3.5 moles of h2