Help me plz quick test

All of the following are part of the biosphere except

What are the first two quantum numbers for the electrons located in subshell 4d? what are the first three quantum numbers for the electrons located in subshell 2s? how many electrons can be held in a sublevel l = 3? how many electrons can be held in the energy level n = 4? how many electrons in an atom can share the quantum numbers n = 4 and l = 3?

Assuming complete dissociation of the solute, how many grams of kno3 must be added to 275 ml of water to produce a solution that freezes at -14.5 c? the freezing point for pure water is 0.0 c and k_f is equal to 1.86 c/m