How many reactants are there in a single replacement reaction?

Astudent reacts 13 moles of iron with 21 moles of oxygen according to the following equation:

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

Asample of tin (ii) chloride has a mass of 0.49 g. after heating, it has a mass of 0.41 g.  what is the percent by mass of water in the hydrate?   %