What “waste” molecule dose photosynthesis make that is so important to put survival?

For the reaction shown, find the limiting reactant for each of the following initial amounts of reactants. 4al(s)+3o2(g)→2al2o3(s) a) 1 molal, 1 mol o2 b) 4 molal, 2.6 mol o2 c) 16 molal, 13 mol o2 d) 7.4 molal, 6.5 mol o2