is a chemical process within cells where sugar and oxygen react to form carbon dioxide and water resulting in the release of energy.

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The internal energy of the system we can term it as total potential energy and kinetic energy. energy flows out of the surrounding from the system then we can say that the internal energy of the final state is lower than its initials. the sign of  δesystem is negative.δesystem = efinal - einitial=-ve  efinal  ∠einitial.