How would i solve this w a bca table lol

What is a possible quantum number set for an electron in the 3s orbital of a magnesium atom

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

When the chemicals iron sulfide (fes) and hydrochloric acid (hcl) are combined, bubbles appear from the mixture. 1. does the appearance of bubbles indicate a physical or chemical change? 2. why do the bubbles indicate this change? 3. what property is this?