Need help ASAP dont really get this

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚c inside a freezer for a night.  when he took it out, its new volume was 322 milliliters, but its pressure was the same.  if the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer? the temperature of the freezer is  kelvins.

What was bohr’s contribution to the planetary model

For the reaction shown, find the limiting reactant for each of the following initial amounts of reactants. 4al(s)+3o2(g)→2al2o3(s) a) 1 molal, 1 mol o2 b) 4 molal, 2.6 mol o2 c) 16 molal, 13 mol o2 d) 7.4 molal, 6.5 mol o2