Help me find the electron dot diagram

Now consider the reaction when 45.0 g naoh have been added. what amount of naoh is this, and what amount of fecl3 can be consumed by it?

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚c inside a freezer for a night.  when he took it out, its new volume was 322 milliliters, but its pressure was the same.  if the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer? the temperature of the freezer is  kelvins.

Calculate the expected ph values of the buffer systems from the experiments (a,b,c,d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.