1. Consider the following equilibrium: Cr2O72-(aq) H2O(l) 2CrO42-(aq) 2H (aq) a. Predict the shift in system at equilibrium if a solution of AgNO3 is added dropwise to the system at equilibrium. Briefly explain.

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :

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