Aldehydes are more reactive than ketones towards nucleophilic addition reactions. Explain why. Steric effect: the carbonyl group of the is connected to which results in a sterically hindered transition state compared to the . Electronic effect: the carbonyl carbon of the is electrophilic than that of the , because the on the carbonyl carbon is stabilized via the inductive effect of compared to the stabilization by in a .

state the principle of separating two immiscible liquids by separating funnel. describe an activity with diagram to separate a mixture of water and kerosene oil. answer: immiscible layers separate out in layers depending on their densities in separating funne

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole

percent abundance for cu-63 can be shown as:

63 x + 65 (1-x) = 62.9296

65 - 62.9296 = 2 x

x = 1.035

thus, percent abundance for cu-63 is 1.035

percent abundance for cu-65 can be shown as:

63 x + 65 (1-x) = 64.9278

65 - 64.9278 = 2 x

x = 0.0361

thus, percent abundance for cu-63 is 0.0361

the mass spectrum of cu-63 showing the intense peak as, this isotope is found in nature more abundantly around 92.38 % in comparison to cu-65 which is found 62.58 % naturally

50.23 i believe is correct but don't quote me on that.