5 questions please help due in 5 minutes

Look at the spectrums of a star moving towards earth and a motionless star. which of these is a correct inference that can be draw from the observation of the two spectrums? (2 points) the spectrum of a motionless star is difficult to be viewed separately using oridinary telescopes. the spectrum of a motionless star is identical to the spectrum of a star which moves towards earth. the spectrum of a star shifts towards the red region when the star moves towards earth. the spectrum of a star shifts towards the blue region when the star moves towards earth.

3. how much energy in joules is required to evaporate .0005 kg of liquid ammonia to vapor at the same temperature? 4. how much energy ( in megajoules ) is given up by .75 kg of water at 0c when it freezes to form ice at 0c? 5. explain how heat works between and at critical temperatures?

Can someone me with 3 and 4 plz. this is for masteries test.