Sort the compounds: conjugated or non conjugated. -but-2-enoic acid -butanoic acid -hex-4-en-3-one -hexan-3-one

But-2-enoic acid and Hex-4-en-3-one are conjugated.

Butanoic acid and Hexan-3-one is non conjugated.

Explanation:

1) Conjugated means system where double bond is present at alternative position separated by single bonds. Conjugation of electrons is present.

But-2-enoic acid is conjugated compound because double bond present at the second carbon is in conjugation with (C=O) bond of carboxylic acid

hex-4-en-3-one are conjugated because double bond present at the forth carbon is in conjugation with third carbon at which oxygen is double bonded.

2) Non conjugated means system where double bonds are not present at alternative position or double bonds are completely absent.

Butanoic acid and Hexan-3-one is non conjugated because conjugation of electrons is absent both the compounds.

Qand k are only the same when the forward rate of the reaction has reached zero.

Moles of co₂ = 2.35/44 = 0.0534 mole.from ideal gas equation pv=nrt,  t = 18+273k = 291 kelvin.∴px5 = 0.0534x0.0821x291∴p = 0.0534x0.0821x291/5 = 0.2551 atm.now, 1 atm = 760 mm of hg  ∴ 0.02551 atm = 0.02551 x 760 = 19.38 mm of hg