How much water is present in 83.0 g of li3po4 * 12h2o?

Which aqueous solution of ki freezes at the lowest temperature? 1) 1 mol of ki in 500. g of water 2) 2 mol of ki in 500. g of water 3) 1 mol of ki in 1000. g of water 4) 2 mol of ki in 1000. g of water