Which step will decrease the pressure of a gas inside a closed cubical container?

You are making a solution of calcium chloride dissolved in water. you add solid, stir, and it dissolves. you add just a spatula tip full, stir, and the solid does not dissolve. how could you describe the solutions before and after adding the spatula tip amount

Lab reagent, hypothesis test.a reference solution used as a lab reagent is purported to have a concentration of 5 mg/dl. six samples are taken from this solution and the following concentrations are recorded: (5.32, 4.88, 5.10, 4.73, 5.15, 4.75) mg/dl.these six measurements are assumed to be an srs of all possible measurements from solution.they are also assumed to have a standard deviation of 0.2, a normal distributin, and a mean concentration equal to the true concentration of the solution.carry out a significance test to determine whether these six measurements provide reliable evidence that the true concentration of the solution is actually not 5 mg/dl.

Under which circumstances are kp and kc equal for the reaction aa(g)+bb(g)⇌cc(g)+dd(g)?