Based on the tiles shown, how many moles of oxygen gas (o2) are needed to produce 36.04 grams of water (h2o) when reacting with excess ethane in the equation 2c2h6 7o2 → 5co2 6h2o?

We calculate for the number of moles of water given its mass by dividing the given mass by the molar mass. 
                               n water = (36.04 g) / (18 g/mol) 
                                n water = 2 mols
From the given balanced equation, every 6 moles of water produced will require 7 moles of oxygen.
                                n oxygen = (2 mols H2O) x (7 moles O2 / 6 moles H2O)
                                n oxygen  = 2.33 mols O2

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.