Given:CH4
P1:828.33 kPa
P2:212.09 kPa
T2:190.49K
Wanted: Kelvins

10-14. (a) when 100.0 ml of weak acid ha were titrated with 0.093 81 m naoh, 27.63 ml were required to reach the equivalence point. find the molarity of ha. (b) what is the formal concentration of a- at the equivalence point? (c) the ph at the equivalence point was 10.99. find pk. for ha. (d) what was the ph when only 19.47 ml of naoh had been added?

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

Predict whether the changes in enthalpy, entropy, and free energy will be positive or negative for the boiling of water, and explain your predictions. how does temperature affect the spontaneity of this process?