For a triprotic acid (H3G) has pKa1 = 2.10, pKa2 = 6.10, pKa3 = 10.10. (A) what's the conjugated base of HV2- ?
(B) At what pH the concentration [H3V-] = [V2-]?
(C) what reagent/s are needed to prepare an pH 10.00 buffer, assuming you have access to strong acid and strong base in addition to the H3V? Describe qualitative how you would prepare the needed pH buffer, and what are the criteria to evaluate whether the pH buffer is good/effective.

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

1. a)c-14 has two more protons

2. d)they have different numbers of protons, neutrons, and valence electrons; they are all gases at room temperature.

3. c) iron and nickel.