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Why are the trends and exceptions to the trends in ionization energy observed?

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

In chemistry, the type of an atom (what element it is) is determined by: a) the number of protons it contains in its nucleus.b) the number of neutrons it contains in its nucleus.c) the number of protons it has in a cloud around the nucleus.d) the number of neutrons it has in a cloud around the nucleus.e) the number of electrons it exchanges with its neighbors.