Cho hỗn hợp hai kim loại Na, Mg (lấy dự) tác dụng với dung dịch HSO4. Biết lượng khí H2 thoát ra bằng 5% khối lượng dung dịch H2SO4 Tính nồng độ phần trăm của dung dịch H2SO4?

As it is given that the initial concentration of sulfuric acid is 0.010 M.

Hence, the ICE table for first dissociation of sulfuric acid is as follows.

Initial:         0.010                       0        0

Change:     -0.010                +0.010    +0.010

Equilibrium:    0                    0.010        0.010

When second dissociation of sulfuric acid occurs which is partial then the ICE table will be as follows.

Initial:                 0.010                    0        0.010

Change:              -x                       +x          +x

Equilibrium:       0.010 - x              x            0.010 + x

Since, it is given that . Hence, formula  for  is as follows.

                               x = 0.0045

Hence, by using the equilibrium concentrations from the table and value of x we get the following.

    = x,        

                   = 0.0045 M

    = 0.010 - x

                     = 0.010 - 0.0045

                     = 0.0055 M

     = 0.010 + x

                   = 0.010 + 0.0045

                   = 0.0145 M

Explanation:

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the product of the pressure and volume is also constant