5. A sample of benzene (C6H6), weighing 7.05 g underwent combustion in a bomb calorimeter by the following reaction: 2 C6H6 (l) + 15 O2 (g) → 12 CO2 (g) + 6 H2O (l)

The heat given off was absorbed by 500 g of water and caused the temperature of the water and the calorimeter to rise from 25.00 to 53.13 oC. The heat capacity of water = 4.18 J/g/oC and the heat capacity of the calorimeter = 10.5 kJ/oC. (1) what is the ΔH of the reaction? Using the definitions at the beginning of the module describe (2) the calorimeter + contents, (3) the type of process.

A sample of benzene (C6H6), weighing 7.05 g underwent combustion in a bomb calorimeter by the following reaction:

2 C6H6 (l) + 15 O2 (g) → 12 CO2 (g) + 6 H2O (l)

The heat given off was absorbed by 500 g of water and caused the temperature of the water and the calorimeter to rise from 25.00 to 53.13 oC. The heat capacity of water = 4.18 J/g/oC and the heat capacity of the calorimeter = 10.5 kJ/oC. (1) what is the ΔH of the reaction?

Explanation:

The heat energy released by the reaction = heat absorbed by calorimeter + heat absorbed by water

Heat absorbed by water = mass of water x specific heat capacity of water x change in temperature

Heat absorbed by water =  500 g x 4.18 J/g. oC x (53.13-25.00)oC

                                         = 58791.7 J

Heat absorbed by calorimeter = heat capacity of calorimeter x change in temperature

Heat absorbed by calorimeter = 10.5 x 10^3 J /oC  x (53.13-25.00)oC

                                                  =295365 J

Total heat energy absorbed = 58791.7 J + 295365 J  = 354156.7 J

Number of moles of benzene given is:

number of moles = goven mass of benzene /its molar mass

=7.05 g / 78.0 g/mol

=0.0903mol

Hence, the heat released by the reaction is:

= 354156.7 J / 0.0903 mol

=  3922.00 kJ/mol

The heat released during the combustion of 7.05g of benzene is 3922.00kJ/mol.                                              

o conteúdo de calor de um sistema é igual à entalpia apenas para um sistema que é constante