2steps of hydrogenation to alkyne to alkane

The melting point of sulfur is 115 °c and its boiling point is 445 °c. what state would sulfur be in at 200 °c?

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.

Imagine one batch of soup (batch “a”) is made with 8.19 g/can of salt, according to the recipe, and a second batch of soup (batch “b”) is made with 8.32 g/can of salt. explain which batch would be more resistant to frost damage if it is shipped a great distance in winter and explain why.