Cyclobutane, C4H8, consisting of molecules in which four carbon atoms form a ring, decomposes, when heated, to give ethylene. The reaction is first order. In an experiment, the initial concentration of cyclobutane was 0.00150 M. After heating at 450°C for 455 s, this was reduced to 0.00119 M. What was the concentration of cyclobutane after a total of 875 s?

The concentration of cyclobutane after 875 seconds is approximately 0.000961 M

Explanation:

The initial concentration of cyclobutane, C₄H₈, [A₀] = 0.00150 M

The final concentration of cyclobutane, [] = 0.00119 M

The time for the reaction, t = 455 seconds

Therefore, the Rate Law for the first order reaction is presented as follows;

Therefore, we get;

Which gives;

k ≈ 5.088 × 10⁻⁴ s⁻¹

The concentration after 875 seconds is given as follows;

[] = [A₀]·

Therefore;

[] = 0.00150 ×  = 0.000961

The concentration of cyclobutane after 875 seconds, [] ≈ 0.000961 M

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