Help please this is due tomorrow and I have a lot to do

Significant figures are digits read directly from the measuring instrument plus one more digit, which is __ by the observer.

The msds for glacial acetic acid says that it is a flammable liquid that can severely burn any human tissue it comes in contact with. it reacts with bases, various metals, and strong oxidizing agents. its vapors can form explosive mixtures with air.

How many moles of lead are in 1.50 x 10^12 atoms of lead? could you explain the answer as well and not just give it to me i am refreshing for finals and i need to know how to do it