A1.00 l sample of water contains 0.0036 g of cl- ions. determine the concentration of chloride ions in ppm if the density of the solution is 1.00 g/ml

Parts-per-million is a form of concentration that is confusing to some. It is often used for aqueous solutions at low concentrations because, as you state in your question, in dilute solutions the density of water has not been affected ie. is still 1.00 g/mL.

parts per million is defined as micrograms of solute per milliliter of solution. This doesn't inherently make sense since micrograms are on the millionths scale, but mL are on the thousandth scale, so it would seem to be millionth per thousandth--Not so! Since the 1.00 mL of water weighs 1.00 g, ug/mL converts, for dilute aqueous solutions, to ug/g, which now makes sense as parts per million. So, from the information given, the calculation is quite simple:

0.0036 g Cl * 10^6 ug/1 g = 3600 ug Cl

1.00 L * 1000 mL/1L = 1000 mL

Concentration of Cl- in solution in ppm:

3600 ug Cl- / 1000 mL = 3.6 ppm Cl-

What’s the question

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.