Chemistry to make tomato soup, you add one can of water to the condensed soup. why is this dilution?

Dilution refers to decreasing the ratio of total solution to the reference solution by the addition of other liquids. By adding water to tomato soup, the balance of “tomato soup” molecules decreases from 100% tomato soup, to eventually 1:1 TS and Water (50%), and so on. Chemically, you can observe this as decreasing the concentration of tomato soup in this solution.

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.

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