The standard reaction enthalpy for the decomposition of cacl2 · nh3(s) into cacl2(s) and nh3(g) is nearly constant at +78 kj mol−1 between 350.k and 470.k. the equilibrium pressure of nh3 in the presence of cacl2 · nh3 is 1.71 kp a at 400.k. find an expression for the temperature dependence of ∆rg◦ m in the same range.

The flow rate of air through a through a pipe is 0.02 m5/s. a pitot static tube is placed in the flow. the radius of the pitot static tube is 1 mm. assuming the flow to be steady and the air to be at 300k, calculate the difference in total and static pressure if the diameter of the pipe is: (a) d 0.1 m d 0.05 m (c) d 0.01 m

Refrigerant-134a enters the compressor of a refrigerator as superheated vapor at 0.14 mpa and -10°c at a rate of 0.05 ka/s and leaves at 0.8 mpa and 50°c. the refrigerant is cooied in the condenser to 0.72 mpa and 26'c. it is then throttled to 0.15 mpa. sketch the t-s diagram for the system and evaluate: 6) the rate of heat removai from the refrigerated space (kw), it) the power input to the compressor (kw), ii) the isentropic efficiency of the compressor (%), and iv) the cop of the refrigerator.

On solidification from a melt, the polymer polyethylene forms a semi-crystalline spherulite structure. (i) sketch an individual spherulite and label the amorphous and crystalline regions. (ii) draw a schematic to show the changes in specific volume with temperature during cooling from the melt, comparing it to the theoretical extremes of fully crystalline and fully amorphous (indicate tm and tg)