Please help me I need to answer this problem

Two flowing streams of argon gas are adiabatically mixed to form a single flow/stream. one stream is 1.5 kg/s at 400 kpa and 200 c while the second stream is 2kg/s at 500 kpa and 100 ? . it is stated that the exit state of the mixed single flow of argon gas is 150 c and 300 kpa. assuming there is no work output or input during the mixing process, does this process violate either the first or the second law or both? explain and state all your assumptions.

The filament of an incandescent lamp has a temperature of 2000k. calculate the fraction of radiation emitted in the visible light band if the filament is approximated as blackbody

A-mn has a cubic structure with a0 0.8931 nm and a density of 7.47 g/cm3. b-mn has a different cubic structure, with a0 0.6326 nm and a density of 7.26 g/cm3. the atomic weight of manganese is 54.938 g/mol and the atomic radius is 0.112 nm. determine the percent volume change that would occur if a-mn transforms to b-mn.