The first-order, gas-phase, reversible reaction A,< B+2C
>
is taking place in a membrane reactor. Pure A enters the reactor, and B diffuses out through the membrane. Unfortunately, a small amount of the reactant A also diffuses through the membrane.
(a) Plot and analyze the flow rates of A, B, and C and the conversion X down the reactor, as well as the flow rates of A and B through the membrane.
(b) Next, compare the conversion profiles in a conventional PFR with those of a membrane reactor from part (a). What generalizations can you make?
(c) Would the conversion of A be greater or smaller if C were diffusing out instead of B?
(d) Discuss qualitatively how your curves would change if the temperature were increased significantly or decreased significantly for an exothermic reaction. Repeat the discussion for an endothermic reaction.
Additional information:
K=10 min^-1 Fao= 100 mol/min
Kc=0.01mol^2/dm^6 v0=100 dm3/min
Kca= 1 min-1 Vreactor= 20dm3
Kcb= 40 min-1