Please can someone help my assignment.

Which pair of angles are vertical angles? ∠1 and ∠4 ∠1 and ∠2 ∠2 and ∠4 ∠2 and ∠3

Will give brainliest summations with algebraic expressions image shown

The appalachian trail is a hiking trail that passes through the appalachian mountains. three members of a teen hiking group hiked a section of the trail. the hikers stopped at a rest area and equally shared 3 4 gallon of water. how much water did each person get?