What happens to the atoms in a liquid as it freezes

Glass is transparent to visibile light under normal conditions; however, at extremely high intensities, glass will absorb most of the light incident upon it. this works through a process known as multiphoton absorption. in this process, several photons are absorbed at the same time. if very intense light whose photons carry 2ev of energy is shined onto a material with a band gap of 4ev, that light can be absorbed through two-photon absorption, because two photons have the right amount of energy to bridge the band gap. what is the minimum number of photons of 800-nm light that are needed to equal or exceed the band gap of fused silica glass

On a day when the barometer reads 75.23 cm, a reaction vessel holds 250 ml of ideal gas at 20 celsius. an oil manometer ( ρ= 810 kg/m^3) reads the pressure in the vessel to be 41 cm of oil and below atmospheric pressure. what volume will the gas occupy under s.t.p.?

Although longitudinal waves can travel through all media types what is the disadvantage of this type of wave transmission? a) he efficiency of he wave transmission is greatly diminished as the media becomes less dense b) the oscillation of one set of particles has a huge impact on neighboring particles c) particles become too close together as they bump into each other making it more likely to hit other particles down the line