The ultracentrifuge is an important tool for separating and analyzing proteins. Because of the enormous centripetal accelerations, the centrifuge must be carefully balanced, with each sample matched by a sample of identical mass on the opposite side. Any difference in the masses of opposing samples creates a net force on the shaft of the rotor, potentially leading to a catastrophic failure of the apparatus. Suppose a scientist makes a slight error in sample preparation and one sample has a mass 10 mg larger than the opposing sample.

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

The rocket is fired vertically and tracked by the radar station shown. when θ reaches 66°, other corresponding measurements give the values r = 32700 ft, r¨ = 85 ft/sec2, and θ˙ = 0.019 rad/sec. calculate the magnitudes of the velocity and acceleration of the rocket at this position.

Consider a hydrogen atom in the ground state. what is the energy of its electron? =e= jj now consider an excited‑state hydrogen atom. what is the energy of the electron in the =5n=5 level? =e5= j