Circular motion is 2d or 3d? Reason.

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Atwo-stage air compressor operates at steady state, compression 10m^3/min of air from 100 kpa and 300k to 1200 kpa. an intercooler between the two stages cools the air to 300k at a constant pressure of 350 kpa. the compression processes are isentropic. a) calculate the power required to run the compressor, in kw b) compare the result to the power required for isentropic compression from the same inlet state to the same final pressure.

Select for each of the following statements whether it is correct or incorrect. (a) in an isothermal expansion of an ideal gas. (b) the temperature remains constant. (b) the pressure remains constant. (c) there is work done by the gas. (d) there is heat added to the gas. (e) the change in internal energy equals zero.