Hi I need help with this question (see image) . Please show workings.

Air is contained in a variable-load piston-cylinder device equipped with a paddle wheel. initially, air is at 400 kpa and 17°c. the paddle wheel is now turned by an external electric motor until 75 kj/kg of work has been transferred to air. during this process, heat is transferred to maintain a constant air temperature while allowing the gas volume to triple. calculate the required amount of heat transfer in kj/kg.

Panel bc in fig. p2.76 is semi-circular, with the 3 meter radius and horizontal straight edge through point b. compute (a) the hydrostatic force of the water on the panel, (b) its center of pressure, and (c) the moment of this force about point b. assume atmospheric pressure on the dry side of the panel

Which component of the earth’s atmosphere is decreased due to photosynthesis?