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The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Learning goal: to understand newton's 1st law. newton's principia states this first law of motion: an object subject to no net force maintains its state of motion, either at rest or at constant speed in a right line. this law may be restated as follows: if the sum of all forces acting on an object is zero, then the acceleration of that object is zero. mathematically this is just a special case of the 2nd law of motion, f⃗ =ma⃗ , when f⃗ =0. when studying newtonian mechanics, it is best to remember the 1st law in two ways: if the net force (i.e., sum of all forces) acting on an object is zero, the object will keep moving with constant velocity (which may be zero). if an object is moving with constant velocity, that is, with zero acceleration, then the net force acting on that object must be zero. complete the following sentences to see if you can apply these ideas. part a if a car is moving to the left with constant velocity, one can conclude that

Which of the following characteristics is fixed, or definite, for all states of matter?