Put these together into the Law of Conservation of Energy

I just need the last one btw

Which best represents the law of conservation of mass ?

Acylinder with a movable piston contains 11.7 moles of a monatomic ideal gas at a pressure of 1.32×10^5 pa. the gas is initially at a temperature of 300 k. an electric heater adds 43200 j of energy into the gas while the piston moves in such a way that the pressure remains constant. cp=20.79 j k^−1 mol^−1 for a monatomic ideal gas, and that the number of gas molecules is equal to avogadro's number (6.022×10^23) times the number of moles of the gas. (a) what is the temperature of the gas after the energy is added? (b) what is the change in volume of the gas? (c) how much work is done by the gas during this process?

Aperson gives a shopping cart an initial push along a horizontal floor to get it moving, and then lets go. the cart travels forward along the floor, gradually slowing as it moves. consider the horizontal force(s) on the cart while it is moving forward and slowing. which of the following statements is correct? (a) both a forward and a backward force are acting on the cart, but the forward force is larger. (b) only a forward force is acting which diminishes with time. (c) both a forward and a backward force are acting on the cart, but the backward force is larger. (d) only a backward force is acting, no forward force.