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As part of an industrial process, air as an ideal gas at 10 bar, 400k expands at steady state through a valve to a pressure of 4 bar. the mass flow rate of air is 0.5 kg/s. the air then passes through a heat exchanger where it is cooled to a temperature of 295k with negligible change in pressure. the valve can be modeled as a throttling process, and kinetic and potential energy effects can be neglected. (a) for a control volume enclosing the valve and heat exchanger and enough of the local surroundings that the heat transfer occurs at the ambient temperature of 295 k, determine the rate of entropy production, in kw/k. (b) if the expansion valve were replaced by an adiabatic turbine operating isentropically, what would be the entropy production? compare the results of parts (a) and (b) and discuss.

1. how much energy is needed to raise the temperature of 40.0 g of argon from 25c to 40c? the specific heat capacity of argon is 0.520 j/(g·k) 2a. 23.0 ml of 0.100 m hcl (standard) are added from a buret to neutralize 50.0 ml of an unknown basic solution. 2b. if the oh- produced in the previous reaction came from ca(oh)2, then what is the molarity of the ca(oh)2? 3.calculate the new freezing-point of a solution when 60.5 grams of cacl2 solute is dissolved in 0.612 kg of water. 4. what is the maximum number of moles of alcl3 that can be produced from 5.0 mol al and 6.0 mol cl2? 5. a sample of oxygen gas has a volume of 150 ml when its pressure is 0.923 atm. if the pressure is increased to 0.987 atm and the temperature remains constant, what will the new volume be? 6. nitrogen gas in a closed container at a temperature of 100.0 oc and 3.0 atm is heated to 300 oc. what is the pressure of the gas at the higher temperature?

Aboy with a mass 25 kg climbs into a small tree. he sits on a branch that is 2.o m above to the ground.what is his gravitational potential energy above the ground?