I need help with these two questions. See attachment

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Two students, each riding bicycles, start from the same apartment building and ride to the same building on campus, but each takes a different route. the first student rides 1100 m due east and then turns due north and travels another 1430 m before arriving at the destination. the second student heads due north for 1930 m and then turns and heads directly toward the destination.at the turning point, how far is the second student from the destination?

Positive ions differ from neutral atoms in that