1. In a magnetic sector (single-focusing) mass spectrometer, it might be reasonable under some circumstances to monitor one m/z value, to then monitor a second m/z, and to repeat this pattern in a cyclic manner. Rapidly switching between two accelerating voltages while keeping all other conditions constant is called peak matching. a) Derive a general expression that related the ratio of the accelerating voltages to the ratio of the corresponding m/z values. b) Use this equation to calculate m/z of unknown peak if m/z of the ion used as a standard, CF3 is 69.00 and the ratio of Vunknown/Vstandard is 0.956134. c) Draw a simple schematics of magnetic sector analyzers d) What causes band broadening in magnetic section analyzers

Juan created a chart to him study for a test. which headings best complete the chart? x: transparent objects y: opaque objects x: opaque objects y: transparent objects x: high frequency waves y: low frequency waves x: low frequency waves y: high frequency waves

5submission this assignment is worth 20 points total. you are required to submit the following by next lab: 1. (3 points) determine the equation for the output angular velocity ω2 = θ˙ 2 as a function of θ1, ω1 = θ˙ 1 and α. you must show all your work to receive credit. 2. (2 points) use the result of problem#1 to plot ω2 over 0 ≤ θ1 ≤ 360deg with ω1 = 360deg/sec. do this for α = {10,30}deg. show the results on the same plot and properly label the axes, title, legend. for this you can use matlab or ms excel. 3. (3 points) determine the equation for the output angular acceleration ω˙ 2 and create a plot similar to the one in problem#2. 4. (10 points) submit plots of the results (ω2 and ω˙ 2) obtained from creo/mechanism and compare them to results of problem#2 and problem#3. note that you should do these comparisons for the two cases with α = {10,30}deg. 5. (2 points) provide a brief explanation of the results. did they match? what are the implications as misalignment angle increases?

Iron is a transition metal with multiple oxidation numbers. (answer the following) a. what is the iron (ii) ion? how does it differ from the iron (iii) ion? b. if iron were to bond with oxygen, predict the formula for each oxidation number of iron. c. how would each formula be named?