Why are group 2 or group 6 elements not used for doping semiconductors​

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An insulated 40 ft^3 rigid tank contains air at 50 psia and 120°f. a valve connected to the tank is now opened, and air is allowed to escape until the pressure inside drops to 25 psia. the air temperature during this process is kept constant by an electric resistance heater placed in the tank. determine the electrical work done during this process.

The experiment done in lab is repeated, using a ball that has unknown mass m. you plot your data in the form of f 2 versus m/l, with f in rev/s, m in kg, and l in m. your data falls close to a straight line that has slope 3.19 m/(kg · s2). use g = 9.80 m/s2 and calculate the mass m of the ball.