Why can't perpetual motion not work on earth?

Why cooking gas has a typical smell

Acoal-fired plant generates 600 mw of electric power. the plant uses 4.8 x 10^6 kg of coal each day, and the heat of combustion of coal is 3.3x 10^7 j/kg. the steam that drives the turbines is at a temperature of 300° c, and the exhaust water is at 37° c. (a) what is the overall efficiency of the plant for generating electric power? (b) how much thermal energy is exhausted each day? (c) what is the change in entropy of the universe for this heat engine? (d) using the same heat reservoirs, what is the maximum possible (carnot) efficiency for a heat engine?

However, had it been a real sound, the sound's pitch would have been increased by the doppler effect, since the falcon was moving the source of the sound. perpendicular to away from towards at the same speed as