The statue of liberty is made of copper that has turned green because it has undergone a change. what can be said about this change?

The copper has undergone an irreversible chemical change called Oxidation

answer: 802.3 kilo joules of energy represents 191.75 kilo calorie of energy.

explanation:

energy released during combustion of one mole methane = 802.3 kilo joules

if 1 kilo joule = 0.239006   kilo calorie

then ,802.3 kilo joule will be = 802.30.239006 kilo calorie

802.3 kilo joule = 191.75 kilo calorie

hence, the energy in kilo calorie is 191.75 kilo calorie.