The maximum solubility of Ag2CO3 in 0.02
M Na2CO3 is (Ksp of
Ag2003 is 8 x 10-12)

The maximum solubility of Ag₂CO₃ = = 1 x 10⁻⁵

Given

0.02 M Na₂CO₃

Ksp of  Ag₂CO₃ is 8 x 10⁻¹²

Required

The solubility of Ag₂CO₃

Solution

Ag₂CO₃ ⇒ 2Ag⁺ + CO₃²⁻

s                  2s        s

s = solubility

Ksp Ag₂CO₃ = [Ag⁺]² [CO₃²⁻]

Ksp Ag₂CO₃ = (2s)².s

Ksp Ag₂CO₃ = 4s³

In 0.02 M Na₂CO₃ ⇒ 2Na⁺ + CO₃²⁻⇒ [ CO₃²⁻]=0.02, so Ksp Ag₂CO₃ :

8 x 10⁻¹² = [2s]² [0.02]

8 x 10⁻¹² = 4s² [0.02]

4s² = 8 x 10⁻¹² / 2 × 10⁻²

4s² = 4 x 10⁻¹⁰

s² = 1 x 10⁻¹⁰

s = √1 x 10⁻¹⁰

s = 1 x 10⁻⁵

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a 20-cm-long, cylindrical graphite (pure carbon) rod is inserted into an oxidizing atmosphere at 1145 k and 1.013 x 105 pa pressure. the oxidizing process is limited by the diffu- sion of oxygen counterflow to the carbon monoxide that is formed on the cylindrical surface.